Mechanistic theoretical proposals for: alkenes by Claisen rearrangement of α-allylthio carbenes; aza-Cope rearrangement of 4-butenyliminium ions; 2-substituted pyrrolidine derivatives; synthesis of perhydrogephyrotoxin, key step; Part V; The Organic Chemistry Notebook, N° 13

José A. Bravo, José L. Vila

Keywords: Organic Chemistry, Alkenes, α-Allylthio carbenes, 4-butenyliminium ions, 2-substituted pyrrolidine derivatives, Perhydrogephyrotoxin, Claisen rearrangement, Aza-Cope rearrangement, Mechanisms of Reactions, W. Carruthers; Claves: Química orgánica, Alquenos, Carbenos de α-aliltio, Iones 4-buteniliminio, Derivados de pirrolidina 2-sustituida, Perhidrogefirotoxina, Reordenamiento de Claisen, Reordenamiento aza-Cope, Mecanismos de reacciones, W. Carruthers.